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- Publications
- Influence
Unification of anion relay chemistry with the Takeda and Hiyama cross-coupling reactions: identification of an effective silicon-based transfer agent.
- A. Smith, Adam T. Hoye, Dionicio Martinez-Solorio, Won-Suk Kim, Rongbiao Tong
- Chemistry, Medicine
- Journal of the American Chemical Society
- 29 February 2012
The unification of Anion Relay Chemistry (ARC) with the Takeda and Hiyama palladium-mediated cross-coupling processes to provide aryl-aryl, alkenyl-aryl, and alkenyl-alkenyl coupled products by… Expand
Asymmetric total syntheses of (-)-penicipyrone and (-)-tenuipyrone via biomimetic cascade intermolecular Michael addition/cycloketalization.
- L. Song, Hongliang Yao, Liangyu Zhu, Rongbiao Tong
- Chemistry, Medicine
- Organic letters
- 4 January 2013
The first total syntheses of (-)-penicipyrone and (-)-tenuipyrone were accomplished enantioselectively in 12 steps with an 11% yield and 6 steps with a 28% yield from the known… Expand
Uniting anion relay chemistry with Pd-mediated cross coupling: design, synthesis and evaluation of bifunctional aryl and vinyl silane linchpins.
- A. Smith, W. Kim, Rongbiao Tong
- Chemistry, Medicine
- Organic letters
- 5 February 2010
Union of type II Anion Relay Chemistry (ARC) with Pd-induced Cross Coupling Reactions (CCR) has been achieved, in conjunction with the design, synthesis, and evaluation of a new class of bifunctional… Expand
Anion relay chemistry: access to the type II ARC reaction manifold through a fundamentally different reaction pathway exploiting 1-oxa-2-silacyclopentanes and related congeners.
- A. Smith, Rongbiao Tong, W. Kim, W. Maio
- Chemistry, Medicine
- Angewandte Chemie
- 12 September 2011
Type I and II anion relay chemistry (ARC)[1] exploiting [1,n]-Brook rearrangements[2] (Scheme 1A and B, respectively), comprise an effective set of synthetic tactics that unite multiple components,… Expand
Benzyl and phenylthiomethyl silanes: a new class of bifunctional linchpins for type II anion relay chemistry (ARC).
- A. Smith, Rongbiao Tong
- Chemistry, Medicine
- Organic letters
- 19 March 2010
A new class of bifunctional linchpins bearing electrophilic sites beta or gamma to a silyl group have been designed, synthesized, and demonstrated to be competent in tricomponent unions exploiting… Expand
Scalable asymmetric total syntheses of (+)-Psoracorylifol B and (+)-ent-Psoracorylifol C.
- J. Ren, Y. Liu, L. Song, Rongbiao Tong
- Chemistry, Medicine
- Organic letters
- 12 May 2014
The first, asymmetric total syntheses of potent antimicrobial Psoracorylifol B (>1.3 g obtained, dr 10.5:1) with a 9.4% overall yield on a gram scale in 14 steps and ent-Psoracorylifol C with a 4.3%… Expand
Total syntheses of durgamone, nakorone, and abudinol B via biomimetic oxa- and carbacyclizations.
- Rongbiao Tong, Jason C. Valentine, F. McDonald, R. Cao, X. Fang, K. Hardcastle
- Chemistry, Medicine
- Journal of the American Chemical Society
- 17 January 2007
The first biomimetic total syntheses of ent-nakorone, ent-durgamone, and ent-abudinol B were accomplished by combining features of tandem polyepoxide cyclization with biomimetic polyene cyclization.… Expand
Biomimetic synthesis via polyepoxide cyclizations
- F. McDonald, Rongbiao Tong, Jason C. Valentine, F. Bravo
- Chemistry
- 2007
The biomimetic synthesis of trans,syn,trans-fused polycyclic ether natural products involving a cascade of stereospecific and regioselective oxacyclizations of polyepoxide substrates is described as… Expand
Cephalosporolide B serving as a versatile synthetic precursor: asymmetric biomimetic total syntheses of cephalosporolides C, E, F, G, and (4-OMe-)G.
- L. Song, Y. Liu, Rongbiao Tong
- Chemistry, Medicine
- Organic letters
- 6 November 2013
Cephalosporolide B (Ces-B) was efficiently synthesized and exploited for the first time as a versatile biomimetic synthetic precursor for the chemical syntheses of not only cephalosporolides C, G,… Expand
Total synthesis and structural revision of (+)-uprolide G acetate.
- Liangyu Zhu, Y. Liu, Renze Ma, Rongbiao Tong
- Chemistry, Medicine
- Angewandte Chemie
- 10 November 2014
The first, asymmetric total synthesis of the proposed structure of (+)-uprolide G acetate (UGA) is reported, and the spectral properties of the synthetic compound clearly differed from those reported… Expand