Roberto Frutos-Pedreño

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The dimeric cyclometalated complexes [Pd2{κ(2)C,N-C6H4CH2CH2C(R)(Me)NH2-2}2(μ-Cl)2] (R = Me (1a), H (1b)) are prepared by reacting 1,1-dimethyl-3-phenylpropylammonium or 1-methyl-3-phenylpropylammonium triflate with Pd(OAc)2 in a 1:1 molar ratio and subsequent treatment with excess NaCl. The mononuclear derivatives [Pd{κ(2)C,N-C6H4CH2CH2C(R)(Me)NH2-2}Cl(L)](More)
The preparation of novel copper(I) complexes of diazabutadiene (DAB) ligands with aliphatic backbones is reported. [Cu(DAB)2](BF4), [Cu(DAB)(NCMe)2](BF4) and [CuCl(DABR)] are easily synthesised and air-stable. These com-
The preparation of novel copper(I) complexes of diazabutadiene (DAB) ligands with aliphatic backbones is reported. [Cu(DAB)2]BF4, [Cu(DAB)(NCMe)2]BF4 and [CuCl(DAB)] are easily synthesised and air stable. These complexes, which remain scarce in the literature, have been fully characterised and their behaviour both in the solid state as well as in solution(More)
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