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The structure of the title tri-fluoro-acetic acid adduct, C17H12N2O3·C2HF3O2, contains a tri-fluoro-acetic acid mol-ecule hydrogen bonded to the imine N atom of the imidazole ring of a nearly planar four-fused-ring system (r.m.s. deviatiation = 0.013 Å). The carb-oxy-lic acid group of the triflouro-acetic acid mol-ecule is twisted with respect to the mean… (More)
The title complex, [CuCl(2)(C(21)H(22)N(4)O)], contains a bis-(benzimidazole) unit with a chiral bridgehead C atom that forms part of a tetra-hydro-pyrrole ring fused to one of the benzimidazoles. The chelate angle is 90.45 (9)° and the dihedral angle between the essentially planar benzimidazole fragments is 26.68 (9)°. The Cu(II) coordination geometry lies… (More)
The title compound, [Co(C(10)H(10)BF(6)N(4))(C(15)H(13)BF(9)N(6))], is a polymorph of the previously reported neutral cobalt(II) complex [Stibrany & Potenza (2010 ▶). Acta Cryst. E66, m506-m507], which contains one each of the monoanionic ligands, bis-[5-methyl-3-(trifluoro-meth-yl)pyrazol-1-yl]borate (Bp) and… (More)
The title compound, [Co(C(10)H(10)BF(6)N(4))(C(15)H(13)BF(9)N(6))], is a neutral Co(II) complex which contains one each of the anionic ligands, bis-(3-trifluoro-methyl-5-methyl-pyrazol-1-yl)borate (Bp) and tris-(3-trifluoro-methyl-5-methyl-pyrazol-1-yl)borate (Tp). A distorted octa-hedral coordination geometry results from ligation of an H atom, which is… (More)