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D-chiro-Inositol is an epimer of myo-inositol that is found in certain mammalian glycosylphosphatidylinositol protein anchors and inositol phosphoglycans possessing insulin-like bioactivity. In order… Continue Reading
trans-1,2-Cycloalkanediols (R,R)-1–4 and (S,S)-1–3 of high optical purities are prepared by enzymatic hydrolysis and esterification catalysed by a lipase from Pseudomonas sp. (SAM II).
Abstract Using a highly enantioselective lipase from Pseudomonas sp. (SAM II) all enantiomers of the isomeric pyridyl-1-ethanols ( R )- and ( S )- 1 – 3 were prepared in optically pure form both by… Continue Reading
3,4-Disubstituted tetrahydrofurans (1)–(4) and (7) of high optical purities have been prepared by enantioselective enzymic hydrolysis of their acetates (±)-(1a)–(4a) and (7a) using a lipase from… Continue Reading
Publisher Summary Lipases are probably at present the most widely used biocatalysts in organic synthesis. Many of them are commercially available, they are frequently stable toward elevated… Continue Reading
L'invention porte sur un procede enzymatique de resolution hydrolytique selective de certains enantiomeres d'un compose pharmaceutique comprenant un melange (±) de derives de l'acide methyl-2… Continue Reading