Robert Büchel

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Reducing the size of low-solubility iron (Fe)-containing compounds to nanoscale has the potential to improve their bioavailability. Because Fe and zinc (Zn) deficiencies often coexist in populations, combined Fe/Zn-containing nanostructured compounds may be useful for nutritional applications. Such compounds are developed here and their solubility in dilute(More)
A novel system for generation of engineered nanomaterials (ENMs) suitable for in situ toxicological characterization within biological matrices was developed. This Versatile Engineered Nanomaterial Generation System (VENGES) is based on industry-relevant, flame spray pyrolysis aerosol reactors that can scaleably produce ENMs with controlled primary and(More)
Vanadium pentoxide (V2O5) nanoparticles (30-60 nm) were made by a one-step and scalable flame spray pyrolysis (FSP) process. Optimization of the FSP processing conditions (precursor concentration and injection rate) enhanced the electrochemical performance of these nanoparticles. Increasing the cut-off potential for discharging from 1.5 to 2.5 V vs. Li/Li+(More)
Crystalline LiMn2O4 nanoparticles with specific surface areas between 53.9 and 203.4 m2 g(-1) (particle size of 25.9-6.9 nm) were produced in a one-step flame spray pyrolysis process by varying the specific combustion enthalpy. An optimized nano-sized powder retained the highest galvanostatic discharge capacity of over 80 mAh g(-1) beyond 60 cycles at 50 C,(More)
Mono- and bimetallic Rh and Pt based NOx storage-reduction (NSR) catalysts, where the noble metals were deposited on the Al2O3 support or BaCO3 storage component, have been prepared using a twin flame spray pyrolysis setup. The catalysts were characterized by nitrogen adsorption, CO chemisorption combined with diffuse reflectance infrared Fourier transform(More)
Named and flamed: Bimetallic Pt-Pd/ZrO(2) catalysts with different Pt/Pd atomic ratios and high dispersion of the metal nanoparticles are prepared by a single-step flame-spray pyrolysis. The catalysts show excellent activity and tunable product selectivity for the solvent-free hydrogenation of the ketone model compounds cyclopentanone and acetophenone.
Core-shell, nano-sized LiFePO(4)-carbon particles were made in one step by scalable flame aerosol technology at 7 g/h. Core LiFePO(4) particles were made in an enclosed flame spray pyrolysis (FSP) unit and were coated in-situ downstream by auto thermal carbonization (pyrolysis) of swirl-fed C(2)H(2) in an O(2)-controlled atmosphere. The formation of(More)
Conventional photocatalytic micromotors are limited to the use of specific wavelengths of light due to their narrow light absorption spectrum, which limits their effectiveness for applications in biomedicine and environmental remediation. We present a multiwavelength light-responsive Janus micromotor consisting of a black TiO2 microsphere asymmetrically(More)
Lead-free piezoelectric nanogenerators made with BaTiO3 offer an attractive energy harvesting solution towards portable, battery-free medical devices such as self-powered pacemakers. Here, we assembled nanogenerators made of thin, flexible poly(vinylidene fluoride-co-hexafluoropropylene) films containing either polycrystalline BaTiO3 nanoparticles of(More)
Superhydrophobic surfaces resisting water penetration into their texture under dynamic impact conditions and offering simultaneously additional functionalities can find use in a multitude of applications. We present a facile, environmentally benign, and economical fabrication of highly electrically conductive, polymer-based superhydrophobic coatings, with(More)
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