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Comprehensive studies of gas-solid reactions require the in-situ interaction of the gas at a pressure beyond the operating pressure of ultrahigh vacuum (UHV) X-ray photoelectron spectroscopy (XPS). The recent progress of near ambient pressure XPS allows to dose gases to the sample up to a pressure of 20 mbar. The present work describes an alternative to(More)
The hydriding kinetics of Pd thin films has been investigated in detail. The in situ experimental technique used in this work consists of a high resolution curvature measurement setup, which continuously monitors the reflections of multiple laser beams reflecting off a cantilevered sample. After mounting the sample inside a vacuum chamber, a H-containing(More)
Water adsorption enhanced catalysis has been recently shown to greatly increase the conversion yield of CO2 methanation. However, the joint catalysis and adsorption process requires new reactor concepts. We measured the spatial water distribution in a model fixed bed reactor using time resolved neutron imaging. Due to the high neutron attenuation(More)
The color changes in chemo- and photochromic MoO3 used in sensors and in organic photovoltaic (OPV) cells can be traced back to intercalated hydrogen atoms stemming either from gaseous hydrogen dissociated at catalytic surfaces or from photocatalytically split water. In applications, the reversibility of the process is of utmost importance, and(More)
Perovskite-type oxides have shown the ability to reversibly segregate precious metals from their structure. This reversible segregation behavior was explored for a commonly used catalyst metal, Ni, to prevent Ni sintering, which is observed on most catalyst support materials. Temperature-programmed reduction, X-ray diffraction, X-ray absorption(More)
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