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Motivated by the necessity to understand the pyrolysis of alkylated amines, unimolecular decomposition of acetamide is investigated herein as a model compound. Standard heats of formation, entropies,(More)
Through the use of a potentially removable tether, a heavily substituted 10b,10c-dimethyl-10b,10c-dihydropyrene (DMDHP), 20, was synthesized exclusively as the cis-isomer. It exists as the major(More)