Raphaël J Durand

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In this article, we describe the synthesis, redox characteristics, and linear and nonlinear optical (NLO) properties of seven new unsymmetrical push-pull diacetylide platinum-based complexes. These D-π-Pt-π-A complexes incorporate pyranylidene ligands as pro-aromatic donor groups (D), diazine rings as electron-withdrawing groups (A), and various aromatic(More)
The reactivity of functionalized ynamides and arylynamines with tetracyanoethylene at room temperature was evaluated. In most cases, the corresponding 1,1,4,4-tetracyanobutadienes (TCBDs) were obtained in good to excellent yields through a [2+2]-cycloaddition/[2+2]-retro-electrocyclization sequence. The influence of diverse functional groups on the yield of(More)
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