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A new ditopic ligand, 4'-(4-(2,2,2-tris(1H-pyrazol-1-ido)ethoxymethyl)phenyl)-2,2':6',2''-terpyridine (pzt), has been prepared and its coordination chemistry studied. Metal ions with a preference for octahedral geometry form ML(2) complexes that are readily isolated and characterised, with the metal ion being bound to the terpyridine sites of both ligands.… (More)
The identity of the metal atom in the paper by Zibaseresht & Hartshorn [Acta Cryst. (2006), E62, i19–i22] is corrected. The published crystal structure in the paper by Zibaseresht & Hartshorn (2006) is almost certainly that of the nickel complex and not the copper complex as originally identified. Refinement of the copper occupancy was consistent with the… (More)