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Hydrogen-bond-accepting (HBA) and -donating (HBD) parameters of ionic liquids (ILs) with halogeno complex anions are determined by means of (1)H NMR spectroscopy. Thereby, the imidazolium cation serves both as part of the IL and as (1)H NMR probe. The HBA and HBD strength are calculated in terms of the empirical polarity parameters β and α according to the… (More)
The reaction of four different basic ionic liquid precursors with Aerosil 300 is presented. Chemisorbed imidazolium and phosphonium cations, with silanolate anions as part of the silicatic support, were obtained and investigated with various solid state NMR techniques.
Aluminum phosphate was deposited onto bundles of carbon fibers and flat glassy carbon substrates using atomic layer deposition by exposing them to alternating pulses of trimethylaluminum and triethylphosphate vapors. Energy dispersive X-ray spectroscopy (EDXS) and solid state nuclear magnetic resonance (SS-NMR) spectra confirmed that the coating comprises… (More)
Solute properties are known to be strongly influenced by solvent molecules due to solvation. This is due to mutual interaction as both the properties of the solute and of the solvent strongly depend on each other. The present paper is based on the idea that ionic liquids are cations solvated by anions and anions solvated by cations. To show this (in this… (More)