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Crown thioether chemistry: synthesis and characterisation of bis(1,4,7-trithiacyclononane)silver(I) trifluoromethanesulphonate, an octahedral homoleptic thioether complex of AgI showing unusually
1,4,7-Trithiacyclononane (9S3) reacts with soluble silver(I) salts to form [Ag(9S3)2]+, a monomeric complex that has a distorted octahedral structure and is readily oxidised to the silver(II) complex.
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Crown thioether chemistry. The silver(I) complexes of trithia-9-crown-3, trithia-12-crown-3, and hexathia-18-crown-6
The coordination chemistry of the three crown thioethers 1,4,7-trithiacyclononane (9S3), 1,5,9-trithiacyclododecane (12S3), and 1,4,7,10,13,16-hexathiacyclooctadecane (18S6) with Ag(I) has beenExpand
  • 61
A new conformation and co-orination mode for 1,4,7-trithiacyclononane (9S3): structure of [Cu2(9S3)3](BF4)2·H2O
Complex [Cu2(9S3)3]2+ contains two {Cu(l)(9S3)} units bond to a third, exodentate 9S3, in the first example of monodentate co-ordination by this ligand.
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N-(4-nitrobenzylidene)-N'-phenylhydrazine.
Molecules of the title compound (alternative name: p-nitrobenzaldehyde phenylhydrazone), C(13)H(11)N(3)O(2), adopt an E configuration about the azomethine C=N double bond. Molecules are approximatelyExpand
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N-(4-Methoxybenzylidene)-N'-(2-pyridyl)hydrazine.
Molecules of the title compound (alternative name p-methoxybenzaldehyde 2-pyridylhydrazone), C(13)H(13)N(3)O, adopt an E configuration about the azomethine C=N double bond. Molecules are almostExpand
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Redox-active crown ethers. Electrochemical and electron paramagnetic resonance studies on alkali metal complexes of quinone crown ethers
Structural studies on [M(NCS)-(SQC-HQDME)] (M=Li, Na) as well as free (QC-HQDME and [M(NCS)((QC-HQDME)] (M=Na, K) (where SQC-HQDME isExpand
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Crystal Structure of N-Benzlidene-N′-(2-carboxyphenyl)hydrazine
Molecules of the title compound (alternative name, benzaldehyde-2-carboxyphenylhydrazone), C14H12N2O2 adopt an E configuration about the azomethine C=N double bond. The molecule is almost planar andExpand
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