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Metal carboxylates with open architectures.
The synthesis, structure, and properties of various types of open-framework metal carboxylates are discussed, for example, cadmium oxalate host lattices that can accommodate extended alkali-metal halide structures. Expand
Direct Observation and Quantification of CO2 Binding Within an Amine-Functionalized Nanoporous Solid
Crystallographic resolution of bound carbon dioxide in a porous solid validates methods of theoretically predicting binding behavior and bodes well for the theory-aided development of amine-based CO2 sorbents. Expand
An amine-functionalized metal organic framework for preferential CO(2) adsorption at low pressures.
A metal organic framework with amine-lined pores gives high values for surface area and heat of adsorption with CO(2) gas.
Facile proton conduction via ordered water molecules in a phosphonate metal-organic framework.
A new phosphonate metal-organic framework (MOF) with a layered motif but not that of the classical hybrid inorganic-organic solid is presented, which contains a polar interlayer lined with Zn-ligated water molecules andosphonate oxygen atoms. Expand
Enhancing water stability of metal-organic frameworks via phosphonate monoester linkers.
The use of phosphonate esters as linkers for the construction of MOFs provides a method to protect hydrolytically susceptible coordination backbones through kinetic blocking. Expand
A single-ligand ultra-microporous MOF for precombustion CO2 capture and hydrogen purification
A single small-ligand–based ultra-microporous MOF showing high CO2 selectivity and PSA working capacity for H2 purification and a high density of binding sites that allow for favorable CO2-CO2 interactions and large cooperative binding energies. Expand
CO2 Laser Direct Written MOF-Based Metal-Decorated and Heteroatom-Doped Porous Graphene for Flexible All-Solid-State Microsupercapacitor with Extremely High Cycling Stability.
  • A. Basu, K. Roy, +5 authors S. Ogale
  • Materials Science, Medicine
  • ACS applied materials & interfaces
  • 11 November 2016
It is argued that the specific attributes of MOF as a precursor and the high-wavelength laser writing approach are together responsible for the peculiar interesting properties of the carbon material thus synthesized, thereby rendering extremely high cycling stability to the corresponding microsupercapacitor device. Expand
Capturing a novel metastable polymorph of the anticancer drug gefitinib
Gefitinib, a life-extending anticancer drug, exhibits solvent-mediated conformational polymorphism to yield stable (form I) and novel metastable (form II) polymorphs. Crystal structure analysisExpand
Hydrogen bonded structures in organic amine oxalates
Oxalates of n-propylamine, n-butylamine, ethylenediamine, 1,4-butanediamine, piperazine, guanidine and 1,4-diazabicyclo[2,2,2]octane (DABCO) have been synthesized and characterized by single crystalExpand