Advances in threshold photoelectron spectroscopy (TPES) and threshold photoelectron photoion coincidence (TPEPICO).
- T. Baer, R. Tuckett
- Physics, ChemistryPhysical Chemistry, Chemical Physics - PCCP
- 12 April 2017
The history and evolution of molecular threshold photoelectron spectroscopy and threshold photoelectron photoion coincidence spectroscopy (TPEPICO) over the last fifty years are reviewed. Emphasis is…
The Role of Atmospheric Gases
- R. Tuckett
- Environmental Science
- 2016
The vacuum-UV absorption spectrum of SF5CF3; implications for its lifetime in the earth's atmosphere
- R. Chim, R. A. Kennedy, R. Tuckett
- Physics
- 10 January 2003
A study of the reactions of trifluoromethyl sulfur pentafluoride, SF5CF3, with several positive ions of atmospheric interest
- C. Atterbury, R. A. Kennedy, C. Mayhew, R. Tuckett
- Chemistry
- 2001
An investigation of the bimolecular reactions of several positive ions of atmospheric interest, H3O+, NO+, NO2+, O2+, H2O+, N2O+, O+, CO2+, CO+, N+ and N2+, with the greenhouse gas SF5CF3 is…
Isomeric effects in the gas-phase reactions of dichloroethene, C2H2CL2, with a series of cations.
- V. Mikhailov, M. Parkes, R. Tuckett, C. Mayhew
- Chemistry, PhysicsJournal of Physical Chemistry A
- 6 April 2006
A study of the reactions of a series of gas-phase cations with the three structural isomers of dichloroethene suggests that the formation of a collision complex at short range between these ions and C(2)H( 2)Cl(2), and hence the threshold for long-range charge transfer, is responsible for the observed effects.
The Kinetics and Dynamics of Elementary Gas-Phase Reactions
- R. Tuckett
- Chemistry, Physics
- 1 September 2002
Abstract : This is an interdisciplinary conference, given in honor of Prof. I.W.M. Smith. Topics include: Reaction Dynamics and Energy Transfer; Gas Kinetics and Atmospheric Chemistry; Astrochemistry…
A halomethane thermochemical network from iPEPICO experiments and quantum chemical calculations.
- J. Harvey, R. Tuckett, A. Bodi
- ChemistryJournal of Physical Chemistry A
- 20 September 2012
Accurate 0 K appearance energies, in conjunction with ab initio isodesmic and halogen exchange reaction energies, establish a thermochemical network, which is optimized to update and confirm the enthalpies of formation of the sample molecules and their dissociative photoionization products.
Dissociation dynamics of fluorinated ethene cations: from time bombs on a molecular level to double-regime dissociators.
- J. Harvey, A. Bodi, R. Tuckett, B. Sztáray
- PhysicsPhysical Chemistry, Chemical Physics - PCCP
- 22 February 2012
The dissociative ionization of C(2)F(4) is found to be comprised of two regimes; at low internal energies, CF(+), CF(3)(+) and CF(2)(+) are formed in statistical processes, and at high internal energies a long-lived excited electronic state is formed, which loses an F atom in a non-statistical process and undergoes statistical redistribution of energy among the nuclear degrees of freedom.
Fragmentation of valence electronic states of CF + 4 and SF + 6 studied by threshold photoelectron-photoion coincidence spectroscopy
- J. C. Creasey, H. Jones, I. Powis
- Physics
- 15 August 1993
Fragmentation of the valence states of CF2Cl2+, CF2H2+, and CF2Br2+ studied by threshold photoelectron–photoion coincidence spectroscopy
- D. Seccombe, R. Tuckett, B. Fisher
- Physics, Chemistry
- 20 February 2001
Using tunable vacuum–ultraviolet radiation from a synchrotron, the decay pathways of the valence electronic states of CF2X2+ (X=Cl, H, Br) in the range 10–25 eV have been determined by threshold…
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