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Aqueous biphasic hydrogenations catalyzed by new biogenerated Pd-polysaccharide species
a b s t r a c t A palladium species bound to an exopolysaccharide (Pd-EPS) was obtained from alive bacterial cells of Klebsiella oxytoca BAS-10 grown in static mode in the presence of Pd(NO3)2.Expand
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Aqueous biphasic treatment of some nitrocompounds with hydrogen in the presence of a biogenerated Pd-polysaccharide.
A strain of Klebsiella oxytoca BAS-10, known to produce a specific exopolysaccharide (EPS), when grown aerobically in static mode in the presence of Pd(NO3)2, generated the species Pd-EPS that wasExpand
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A new biogenerated Rh-based catalyst for aqueous biphasic hydroformylation
Abstract A new bio-generated rhodium based system embedded in a peculiar polysaccharide matrix (Rh-EPS), was obtained and purified from cultures of bacterial cells of Klebsiella oxytoca DSM 29614.Expand
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Novel iron and gallium salts of Aquivion® PFSA: Synthesis, characterization and some catalytic applications
Abstract The objective of this study was to prepare, characterize and test the catalytic properties of iron and gallium salts of Aquivion ® PFSA (hereinafter Aquivion-H). The samples wereExpand
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Hydrodechlorination of Aroclor 1260 in Aqueous Two-phase Mixture Catalyzed by Biogenerated Bimetallic Catalysts
The PCBs are known recalcitrant and toxic pollutants and significant values of contamination could be found in water. PCBs can be hydrodechlorinated using Pd-based catalysts and hydrogen, but theExpand
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Studio di sistemi catalitici innovativi per la sintesi di prodotti della chimica fine
The aim of this work of thesis was the synthesis, characterization and use of new catalytic species used in different type of reaction, by using model substrates in order to understand the advantagesExpand
Aqueous-phase hydrogenation and hydroformylation reactions catalyzed by a new water-soluble (rhodium)-thioligand complex
Abstract Rh(DHTANa) is a new water-soluble catalyst easily obtained by mixing in water the catalytic precursor [Rh(COD)Cl] 2 and the dihydrothioctic acid sodium salt (DHTANa). This catalyst showed toExpand
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