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In the title compound, C17H16O4, the dihedral angle between the mean planes of the hydroxyphenyl and dimethoxyphenyl rings is 5.9 (6)°. The mean plane of the prop-2-en-1-one group makes dihedral
Spectroscopic, structural and antibacterial properties of copper(II) complexes with bio-relevant 5-methyl-3-formylpyrazole N(4)-benzyl-N(4)-methylthiosemicarbazone
X-ray crystallography of a representative species, [Cu(HMPz4BM)(NO3)2] (C2/c, monoclinic ), has unambiguously documented the conjectural findings from i.r.r parameters (RT and LNT) of the reported copper(II) complexes are indicative of a dxx2–y2 ground state for the reported species.
While no classical hydrogen bonds are present, weak intermolecular C—H⋯π-ring interactions are observed, which contribute to the stability of crystal packing.
Redetermination of 4-hydroxybenzaldehyde
This is a redetermination of the structure of the title compound, C7H6O2, which was first reported by Iwasaki in 1977 and obtained with greater precision in the present study.
Design of a Series of Isostructural Co-Crystals with Aminopyrimidines: Isostructurality through Chloro/Methyl Exchange and Studies on Supramolecular Architectures
A series of 17 co-crystals involving 2-amino-4-chloro-6-methyl pyrimidine/2-amino-4,6-dimethyl pyrimidine with various carboxylic acids, C7H5O2-R (where R = H, Cl, CH3, NO2, OCH3, COOH) and C9H8O2,
Bi- and trinuclear copper(II) complexes of a sterically constrained phenol-based tetradentate ligand: syntheses, structures, and magnetic studies.
It appears to be a rare example of a phenolato-bridged Cu(II) dimer exhibiting ferromagnetic interactions, a behavior in agreement with the theoretical predictions but seldom observed experimentally.