R Rico-Ferreira

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The total synthesis of the growth regulators (+)-ampullicin 1 and (+)-isoampullicin 2 from (R)-(-)-carvone 5 was accomplished by application of an 18-step sequence with 4.5% overall yield. The crucial step of the synthetic strategy lies on the internal displacement of tosylate 13 by means of the lactone enolate. In this way, access was opened to the(More)
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