Régis Gautier

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The bottom-up synthesis of organometallic zinc clusters is described. The cation {[Zn10](Cp*)6 Me}(+) (1) is obtained by reacting [Zn2 Cp*2] with [FeCp2][BAr4 (F)] in the presence of ZnMe2. In the presence of suitable ligands, the high reactivity of 1 enables the controlled abstraction of single Zn units, providing access to the lower-nuclearity clusters(More)
The structure of scandium dirubidium pentadecamolybdenum nonadecasulfide, Sc(0.43(2))Rb(2)Mo(15)S(19), constitutes a partially Sc-filled variant of Rb(2)Mo(15)S(19) [Picard, Saillard, Gougeon, Noel & Potel (2000), J. Solid State Chem. 155, 417-426]. In the two compounds, which both crystallize in the R ̅3c space group, the structural motif is characterized(More)
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