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Symmetry-Supported Magnetic Blocking at 20 K in Pentagonal Bipyramidal Dy(III) Single-Ion Magnets.
- Y. Chen, J. Liu, +7 authors M. Tong
- Medicine, Physics
- Journal of the American Chemical Society
- 17 February 2016
Single-molecule magnets (SMMs) that can be trapped in one of the bistable magnetic states separated by an energy barrier are among the most promising candidates for high-density information storage,… Expand
Dynamic Magnetic and Optical Insight into a High Performance Pentagonal Bipyramidal DyIII Single-Ion Magnet.
The pentagonal bipyramidal single-ion magnets (SIMs) are among the most attractive prototypes of high-performance single-molecule magnets (SMMs). Here, a fluorescence-active phosphine oxide ligand… Expand
"Half-sandwich" Yb(III) single-ion magnets with metallacrowns.
The first "half-sandwich" Yb(III) single-ion magnets (SIMs) based on [12-MCZn(ii)-4] are reported, in which the central ytterbium ion is coordinated by YbO8 geometry in D4d symmetry. The anisotropic… Expand
Anisotropy rather than transverse isotropy in Longmaxi shale and the potential role of tectonic stress
Abstract In the last few decades, the recovery of and exploration for shale gas has increased. This has led to increased interest in the mechanical characterization of shale formations as relates to… Expand
A zigzag DyIII4 cluster exhibiting single-molecule magnet, ferroelectric and white-light emitting properties
A novel multifunctional complex [Dy4(OH)2(bpt)4(NO3)6(EtOH)2]·EtOH (1, Hbpt = 3,5-bis(pyridin-2-yl)-1,2,4-trizolate) was designed, based on the self-assembly under hydrothermal conditions, and it… Expand
Two 3d-4f nanomagnets formed via a two-step in situ reaction of picolinaldehyde.
Two 3d-4f nanomagnets, [Dy(III)2Cu(II)7] (1) and [Gd(III)6Cu(II)12] (2), are synthesized under a two-step in situ reaction of picolinaldehyde. Not only the final adduct (hemiacetal), but also the… Expand
Fluorescent single-ion magnets: molecular hybrid (HNEt₃)[DyxYb1-x(bpyda)₂] (x = 0.135-1).
Four single-phase isostructural mononuclear complexes (HNEt₃)[DyxYb1-x(bpyda)2]·3H₂O (x = 1 (1), 0 (2), 0.367 (3), 0.135 (4), bpyda = 2,2'-bipyridine-6,6'-dicarboxylate) show characteristics of… Expand
Luminescent single-molecule magnets based on lanthanides: Design strategies, recent advances and magneto-luminescent studies
Abstract Incorporation of two characters into one molecular entity is an effective way to afford bifunctional molecule-based materials. Lanthanides serve as a group of preferable objectives for the… Expand
Magnetocaloric Properties of Heterometallic 3d-Gd Complexes Based on the [Gd(oda)3 ](3-) Metalloligand.
- Jiang-Zhen Qiu, Long-fei Wang, Y. Chen, Z. Zhang, Quanwen Li, M. Tong
- Medicine, Chemistry
- 11 January 2016
A series of heterometallic 3d-Gd(3+) complexes based on a lanthanide metalloligand, [M(H2 O)6 ][Gd(oda)3 ]⋅3 H2 O [M=Cr(3+) (1-Cr)] (H2 oda=2,2'-oxydiacetic acid), [M(H2 O)6 ][MGd(oda)3 ]2 ⋅3 H2 O… Expand
Unprecedented hexagonal bipyramidal single-ion magnets based on metallacrowns.
- Quanwen Li, Rui-Chen Wan, +5 authors M. Tong
- Chemistry, Medicine
- Chemical communications
- 8 November 2016
Two Ln(iii) (Ln = Ce or Nd) complexes based on [15-MC-6] (MC = metallacrown) and phosphine oxide are reported for the first time with the Ln(iii) ion featuring nearly perfect hexagonal bipyramidal… Expand