Qiu Tian Liu

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The novel title double-butterfly Fe/S cluster complex, [Fe(4)(C(4)H(8)S(2))(2)(CO)(12)], which is structurally similar to the active site of the Fe-only hydrogenases, contains two inversion-related Fe(2)S(2)(CO)(6) subcluster cores connected by two equivalent butyl chains to afford a 16-membered macrocycle. The formation of the 16-membered macrocycle has an(More)
In the title compound, [Mn(C(7)H(3)NO(4))(C(3)H(4)N(2))(C(12)H(8)N(2))(H(2)O)], the Mn(II) centre is surrounded by one bidentate phenanthroline ligand [Mn-N = 2.383 (3) and 2.421 (3) A], one tridentate dipicolinate ligand [Mn-N = 2.300 (3) A, and Mn-O = 2.300 (2) and 2.357 (2) A], one monodentate imidazole ligand [Mn-N = 2.238 (3) A] and one water molecule(More)
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