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Synthesis Structures, and Properties of Functional 2-D Lanthanide Coordination Polymers [Ln2(dpa)2(C2O4)2(H2O)2]n (dpa = 2,2′-(2-methylbenzimidazolium-1,3-diyl)diacetate, C2O42− = oxalate, Ln = Nd,
Four two-dimensional frameworks {[Nd(dpa)(C2O4)(H2O)]·(H2O)}n (1), {[Ln2(dpa)2(C2O4)2(H2O)2]·(H2O)}n (Ln = Eu (2), Gd (3), Tb (4)) (dpa = 2,2′-(2-methylbenzimidazolium-1,3-diyl)diacetate, C2O42− =Expand
4,4′-Di­thio­diphenol: a chain of rings generated by two pairs of O—H⋯O hydrogen bonds
In the title compound, C12H10O2S2, mol­ecules are linked into chains by two pairs of O—H⋯O hydrogen bonds [H⋯O = 1.99 (2) A, O⋯O = 2.759 (2) and 2.783 (2) A and O—H⋯O = 162 and 165 (2)°]. FourExpand
Nanospheric [M20(OH)12(maleate)12(Me2NH)12]4+ clusters (M = Co, Ni) with O(h) symmetry.
Nanospheric hydroxo-bridged clusters of [M(20)(OH)(12)(maleate)(12)(Me(2)NH)(12)](BF(4))(3)(OH)·nH(2)O (M = Co (1), Ni (2)) with O(h) symmetry were afforded under hydrothermal condition withExpand
π-Stacking induced complexes with Z-shape motifs featuring a complementary approach between electron-rich arene diamines and electron-deficient aromatic N-heterocycles
Based on ligands of N,N′-bis((diphenylphosphino)methyl)benzene-1,4-diamine (L1) and N,N′-bis((diphenylphosphino)methyl)naphthalene-1,5-diamine (L2), six complexes ofExpand
Synthesis, structural characterization and luminescent properties of a series of Cu(I) complexes based on polyphosphine ligands.
A series of Cu(I) complexes with a [Cu(NN)(PP)](+) moiety, [Cu(phen)(pba)](BF(4)) (1a), [Cu(2)(phen)(2)(pbaa)](BF(4))(2) (2a), [Cu(2)(phen)(2)(pnaa)](BF(4))(2) (3a), [Cu(2)(phen)(2)(pbbaa)](BF(4))(2)Expand
Synthesis, structures and characterization of a series of Cu(I)-diimine complexes with labile N,N′-bis((diphenylphosphino)methyl)naphthalene-1,5-diamine: diverse structures directed by π–π stacking
Five complexes [Cu2(phen)2(dpna)](ClO4)2 (1), [Cu2(dmp)2(dpna)](ClO4)2 (2), {[Cu(phen)(dpna)](ClO4)}n (3), [Cu2(pz)(dpna)](ClO4)2 (4) and [Cu2(pz)(dpna)2](ClO4)2 (5) (phen = 1,10-phenanthroline, dmpExpand
[Ag15(N-triphos)4(Cl4)](NO3)3: a stable Ag-P superatom with eight electrons (N-triphos = tris((diphenylphosphino)methyl)amine).
A first and stable Ag-P superatom nanocluster [Ag15(N-triphos)4(Cl4)](NO3)3 (1) has been successfully synthesized and characterized. X-ray analysis shows that this Ag15 cluster has a hexacappedExpand
Assembly molecular architectures based on structural variation of metalloligand [Cu(PySal)2] (PySal = 3-pyridylmethylsalicylideneimino)
Abstract A versatile neutral metalloligand [Cu(PySal)2] (1) (PySal = 3-pyridylmethylsalicylidene-imino) was exploited as a building unit to construct five complexes {Cu[Cu(PySal)2]2}(ClO4)2 (2),Expand
Rare double spin canting antiferromagnetic behaviours in a [Co24] cluster.
A fish-basket-shaped [Co24] cluster, [Co24(μ3-O)4(ampc)4(μ3-OH)4(μ2-OH)4(NO3)5(HCO2)22(H2O)10]·[(HCO2)·2(CH3OH)·x(H2O)], was woven by bridging oxygen atoms from O(2-), OH(-), NO3(-) and HCO2(-)Expand
Gold(I) Chloride Complexes of Polyphosphine Ligands with Electron-Rich Arene Spacer: Gold–Arene Interactions
The reactions of Au(tht)Cl (tht = tetrahydrothiophene) with the electron-rich-arene-spacer-containing polyphosphine ligands N,N′-bis((diphenylphosphino)methyl)benzene-1,4-diamine (Dpba),Expand
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