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Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies
Lanthanide Single Molecule Magnets
A Basis for Lanthanide Single Molecule Magnets.- Lanthanide Single Ion Molecule Magnets.- Dinuclear Lanthanide Single Molecule Magnets.- Single-molecule Toroics and Multinuclear Lanthanide Single…
Polynuclear Lanthanide Single Molecule Magnets
Equatorially coordinated lanthanide single ion magnets.
- Peng Zhang, Li Zhang, Chao Wang, Shufang Xue, Shuang-Yan Lin, Jinkui Tang
- PhysicsJournal of the American Chemical Society
- 17 March 2014
The three-coordinate Er-based complex is the first equatorially coordinated mononuclear Er- based single-molecule magnet (SMM) corroborating that simple models can effectively direct the design of target SMMs incorporating 4f-elements.
Modulating magnetic dynamics of Dy2 system through the coordination geometry and magnetic interaction.
- Peng Zhang, Li Zhang, Shuang-Yan Lin, Shufang Xue, Jinkui Tang
- Materials ScienceInorganic chemistry
- 25 March 2013
The comparison of the structural parameters among the similar Dy2 SMMs with hula hoop-like geometry reveals the significant role played by coordination geometry and magnetic interaction in modulating the relaxation dynamics of SMMs.
Tetranuclear [MDy]2 compounds and their dinuclear [MDy] (M = Zn/Cu) building units: their assembly, structures, and magnetic properties.
The result suggests the positive effects of coupling blocking units to enhance their SMM behavior, presenting a promising strategy for constructing efficient heterometallic SMMs.
Macrocyclic ligand encapsulating dysprosium triangles: axial ligands perturbed magnetic dynamics.
Two Dy(3) triangles encapsulated inside the cavity of a macrocycle ligand have been successfully synthesized, providing a unique opportunity to probe the relaxation dynamics of the complexes by…
Lanthanide Single Molecule Magnets: Progress and Perspective
Lanthanide single molecule magnets: progress and perspective.
The last few years have seen a huge renaissance in the study of single molecule magnets (SMMs) thanks to the extensive applications of lanthanide ions with large inherent anisotropy in molecular…
Two new Dy3 triangles with trinuclear circular helicates and their single-molecule magnet behavior.
- Shuang-Yan Lin, Lang Zhao, Yun-Nan Guo, Peng Zhang, Yang Guo, Jinkui Tang
- ChemistryInorganic chemistry
- 17 April 2012
Self-assembly of polydentate Schiff base 2,6-diformyl-4-methylphenol di(benzoy1hydrazone) (H(3)L), with dysprosium thiocyanate and sodium azide, affords two novel trinuclear triangular circular helicate dysProsium(III) complexes, revealing multiple relaxation processes and the onset of slow magnetization relaxation occur for complex 1 and 2.