P. Rigo

Publications167
h-index35
Citations3,642
Highly Influential Citations23
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Whole-body 18FDG positron emission tomography in the staging of non-small cell lung cancer.
Despite advances in morphological imaging, some patients with lung cancer are found to have nonresectable disease at surgery or die of recurrence within yr of surgery. We performed a prospective… Expand
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Positron emission tomography (PET) with 18F-fluorodeoxyglucose (18F-FDG) for the staging of low-grade non-Hodgkin's lymphoma (NHL).
BACKGROUND Although PET has been shown to be highly sensitive in the primary staging of lymphoma, previous studies with small numbers of patients indicated that low-grade NHL may not always be… Expand
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Very Fast Suzuki–Miyaura Reaction Catalyzed by Pd(OAc)2 under Aerobic Conditions at Room Temperature in EGME/H2O
The results of a ligand-free Pd(OAc)2-catalyzed Suzuki–Miyaura C–C coupling performed at room temperature under aerobic conditions are presented. It was found that the use of an ethylene glycol… Expand
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2-(Aminomethyl)pyridine−Phosphine Ruthenium(II) Complexes: Novel Highly Active Transfer Hydrogenation Catalysts
The complexes trans,cis-RuCl2(PPh3)2(ampy) (1) and trans-RuCl2[Ph2P(CH2)4PPh2](ampy) (2) have been prepared in high yield by reaction of RuCl2(PPh3)3 and RuCl2(PPh3)[Ph2P(CH2)4PPh2] with… Expand
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Osmium(II) CNN pincer complexes as efficient catalysts for both asymmetric transfer and H2 hydrogenation of ketones.
We describe the isolation of the first CNN pincer osmium complexes [OsX(CNN)P 2 ] to display high catalytic activity and productivity in the reduction of ketones by either TH or HY (TOFand TON up… Expand
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Cyclopentadienyl RuII Complexes as Highly Efficient Catalysts for the N‐Methylation of Alkylamines by Methanol
The ruthenium(II) half-sandwich complex [RuCl(η5-C5H5)(PPh3)2] (1) catalyses the reaction between methanol and alkylamines RNH2 or R1R2NH to afford RN(CH3)2 and R1R2NCH3 products, respectively. The… Expand
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Highly productive CNN pincer ruthenium catalysts for the asymmetric reduction of alkyl aryl ketones.
Chiral pincer ruthenium complexes of formula [RuCl(CNN)(Josiphos)] (2-7; Josiphos = 1-[1-(dicyclohexylphosphano)ethyl]-2-(diarylphosphano)ferrocene) have been prepared by treating… Expand
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Efficient chemoenzymatic synthesis of chiral pincer ligands.
Chiral, nonracemic pincer ligands based on the 6-phenyl-2-aminomethylpyridine and 2-aminomethylbenzo[h]quinoline scaffolds were obtained by a chemoenzymatic approach starting from 2-pyridyl and… Expand
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C-H activation and C=C double bond formation reactions in iridium ortho-methyl arylphosphane complexes.
The Vaska-type iridium(I) complex [IrCl(CO){PPh(2)(2-MeC(6)H(4))}(2)] (1), characterized by an X-ray diffraction study, was obtained from iridium(III) chloride hydrate and PPh(2)(2,6-MeRC(6)H(3))… Expand
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Dioxygen addition to five-coordinate osmium(II) complexes. X-Ray crystal structure of [OsH(η2-O2)(dcpe)2]bph4[dcpe = 1,2-bis(dicyclohexylphosphino)ethane]
The five-coordinate osmium(II) cations [OsX(dcpe)2]+[X = H or Cl; dcpe = 1,2-bis(dicyclohexylphosphino)ethane] react with dioxygen in 1 : 1 molar ratio giving the stable peroxo complexes… Expand
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