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Modern rhodium-catalyzed organic reactions
Foreword.Preface.List of Contributors.1 Rhodium-Catalyzed Asymmetric Hydrogenation (Yongxiang Chi, Wenjun Tang, and Xumu Zhang).1.1 Introduction.1.2 Chiral Phosphorous Ligands.1.3 Applications ofExpand
Asymmetric dihydroxylation of vinyl sulfones: routes to enantioenriched α-hydroxyaldehydes and the enantioselective syntheses of furan-2(5H)-ones
The asymmetric dihydroxylation of α,β-unsaturated sulfones under Sharpless conditions affords enantioenriched α-hydroxyaldehydes in a complex mixture of dimeric species. These mixtures undergoExpand
Stereoselective transition metal-catalysed higher-order carbocyclisation reactions.
This tutorial review details the historical development of higher-order carbocyclisation reactions, specifically the variants of [m+2+2] that involve carbon-based pi-systems, where m = 2, 3 and 4, in the context of critical developments with various transition metal complexes. Expand
Diastereoselective construction of syn-1,3-dioxanes via a bismuth-mediated two-component hemiacetal/oxa-conjugate addition reaction.
The bismuth-mediated two-component hemiacetal/oxa-conjugate addition of δ-trialkylsilyloxy and δ-hydroxy α,β-unsaturated aldehydes and ketones with alkyl aldehydes provides the syn-1,3-dioxanes in aExpand