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Modern rhodium-catalyzed organic reactions
- P. Evans
Foreword.Preface.List of Contributors.1 Rhodium-Catalyzed Asymmetric Hydrogenation (Yongxiang Chi, Wenjun Tang, and Xumu Zhang).1.1 Introduction.1.2 Chiral Phosphorous Ligands.1.3 Applications of… Expand
Rhodium(I)‐Catalyzed Allylic Substitution Reactions and Their Applications to Target Directed Synthesis
Asymmetric dihydroxylation of vinyl sulfones: routes to enantioenriched α-hydroxyaldehydes and the enantioselective syntheses of furan-2(5H)-ones
The asymmetric dihydroxylation of α,β-unsaturated sulfones under Sharpless conditions affords enantioenriched α-hydroxyaldehydes in a complex mixture of dimeric species. These mixtures undergo… Expand
Conservation of Absolute Configuration in the Acyclic Rhodium-Catalyzed Allylic Alkylation Reaction: Evidence for an Enyl (σ + π) Organorhodium Intermediate.
Stereoselective Construction of cis-2,6-Disubstituted Tetrahydropyrans via the Reductive Etherification of δ-Trialkylsilyloxy Substituted Ketones: Total Synthesis of (-)-Centrolobine.
Enantioselective Total Synthesis of the Nonisoprenoid Sesquiterpene (‐)‐Kumausallene.
Regioselective rhodium-catalyzed allylic linchpin cross-coupling reactions: diastereospecific construction of anti-1,3-carbon stereogenic centers and C(2)-symmetrical fragments.
Stereoselective transition metal-catalysed higher-order carbocyclisation reactions.
This tutorial review details the historical development of higher-order carbocyclisation reactions, specifically the variants of [m+2+2] that involve carbon-based pi-systems, where m = 2, 3 and 4, in the context of critical developments with various transition metal complexes. Expand
Modern Rhodium-Catalyzed Organic Reactions: EVANS:RHODIUM O-BK
- P. Evans
- 5 August 2005
Diastereoselective construction of syn-1,3-dioxanes via a bismuth-mediated two-component hemiacetal/oxa-conjugate addition reaction.
- P. Evans, Aleksandr Grisin, M. Lawler
- Chemistry, Medicine
- Journal of the American Chemical Society
- 1 February 2012
The bismuth-mediated two-component hemiacetal/oxa-conjugate addition of δ-trialkylsilyloxy and δ-hydroxy α,β-unsaturated aldehydes and ketones with alkyl aldehydes provides the syn-1,3-dioxanes in a… Expand