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The synthesis and biological activity profiling of a large series of diverse pyrrolo[2,3-d]pyrimidine 4'-C-methylribonucleosides bearing an (het)aryl group at position 4 or 5 is reported as well as… Continue Reading
Only in the case of the methoxycarbonylation the yields of (XI) can be improved by using dppf instead of PPh3 as a ligand.
Aminohydroxylation of prochiral divinylcarbinol and subsequent Pd(II)-catalysed oxy-/amidocarbonylation of aminopentenediols is reported. The method was applied to the preparation of useful building… Continue Reading
We have identified reaction conditions for a Heck-type carbonylation based on [Fe(CO)5]. Preliminary optimization of alkoxycarbonylation on 2-bromonaphthalene defined functioning composition of the… Continue Reading
Novel analogues of (+)-varitriol have been synthesised via Julia-Kocienski olefination from -Dribonolactone. Newly prepared compounds were screened for their in vitro cytotoxicity towards certain… Continue Reading