Nozipho M. Khumalo

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In the binuclear centrosymmetric title compound, [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·0.35H(2)O, a pseudo-polymorph of [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·2CH(3)CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio-cyanate ligands in a distorted tetra-hedral configuration. The crystal structure exhibits inter-molecular C-H⋯π inter-actions.
In (η⁶-p-cymene)(difluorophosphinato-κO){2-[(1H-pyrazol-1-yl)methyl-κN²]pyridine-κN}ruthenium(II) 0.85-hexafluorophosphate 0.15-tetrafluoroborate, [Ru(PO₂F₂)(C₁₀H₁₄)(C₉H₉N₃)](PF₆)0.85(BF₄)0.15, (I), the [PO₂F₂]⁻ ligand exhibits positional disorder due to one F atom and one O atom sharing the same two positions related by a mirror reflection across the O-P-F(More)
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