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An equation of state for the Ñuid phase of nonattracting rigid particles of arbitrary shape is presented. A particle shape factor is deÐned and its dependence on the packing fraction is evaluated from Monte Carlo and molecular dynamics simulation results for a variety of nonattracting asymmetric rigid particles,
An equation of state for the multicomponent fluid phase of nonattracting rigid particles of arbitrary shape is presented. The equation is a generalization of a previously presented equation of state for pure fluids of rigid particles; the approach describes the volumetric properties of a pure fluid in terms of a shape factor, zeta, which can be back… (More)