Norbert S Chilingarov

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Saturated vapor pressure p° and enthalpy of sublimation (ΔsH°) of cerium tetrafluoride CeF4 were determined by means of Knudsen effusion mass spectrometry in the range of 750-920 K. It was discovered that sublimation of cerium tetrafluoride from a platinum effusion cell competes with thermal decomposition to CeF3 in the solid phase, but no accompanying(More)
High-temperature chlorination of C90 -containing fullerene fraction resulted in the isolation and X-ray structural characterization of C90 (1)Cl10/12 , the first derivatives of a relatively unstable isomer D5h -C90 (1) with a nanotubular shape. In the crystal structure, three isomers of both C90 (1)Cl10 and C90 (1)Cl12 with similar chlorination patterns(More)
Knudsen cell mass spectrometry was applied to the evaluation of the ionization efficiency curves for the ions originating from CoF(4) molecules. Cobalt tetrafluoride was obtained in the gas phase over the CoF(3)(s)-TbF(4)(s) system in the temperature range from 640 to 690 K. From the ionization efficiency curves the appearance energies of the ions formed(More)
RATIONALE Ionic liquids ([Cat(+)][An(-)]) were believed to decompose before reaching vaporization temperatures, but recently some of them have been shown to vaporize congruently. Low-temperature vaporization of ionic substances is an intriguing phenomenon, so the vapor-phase composition and reactions of ionic liquids deserve more extensive study. METHODS(More)
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