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Synthesis of a "Masked" Terminal Nickel(II) Sulfide by Reductive Deprotection and its Reaction with Nitrous Oxide.
The addition of 1 equiv of KSCPh3 to [L(R)NiCl] (L(R) = {(2,6-iPr2C6H3)NC(R)}2CH; R = Me, tBu) in C6H6 results in the formation of [L(R)Ni(SCPh3)] (1: R = Me; 2: R = tBu) in good yields. SubsequentExpand
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Activation of CS2 by a "masked" terminal nickel sulfide.
The "masked" terminal nickel sulfide complexes [K(L)][(L(tBu))Ni(II)(S)] (L(tBu) = {(2,6-(i)Pr2C6H3)NC((t)Bu)}2CH, L = 18-crown-6, 2,2,2-cryptand) activate CS2 to give the trithiocarbonate productsExpand
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Reactivity of a Nickel Sulfide with Carbon Monoxide and Nitric Oxide.
The reactivity of the "masked" terminal nickel sulfide complex, [K(18-crown-6)][(L(tBu))Ni(II)(S)] (L(tBu) = {(2,6-(i)Pr2C6H3)NC((t)Bu)}2CH), with the biologically important small molecules CO andExpand
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Trapping of an NiII Sulfide by a CoI Fulvene Complex
The reaction of [LtBuNiII(SCPh3)] (LtBu = {(2,6-iPr2C6H3)NC(tBu)}2CH) with Cp*2Co yields a NiI cobaltocenium thiolate complex, [LtBuNiI(SCH2Me4C5)Co(Cp*)] (1), along with HCPh3. Formation of thisExpand
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ctivity of a nickel ( II ) thioperoxide complex : demonstration of sul fi de-mediated N 2 O reduction †
The thiohyponitrite ([SNNO] ) complex, [K(18-crown-6)][LNi(k-SNNO)] (L 1⁄4 {(2,6-Pr2C6H3) NC(Bu)}2CH), extrudes N2 under mild heating to yield [K(18-crown-6)][L Ni(h-SO)] (1), along with minorExpand
Synthesis, Characterization, and Reactivity of "Masked" Terminal Nickel Sulfides
Author(s): Hartmann, Nathaniel James | Advisor(s): Hayton, Trevor W | Abstract: Treatment of the Ni(II) chloride complexes, [LRNiIICl] (LR = {(2,6-iPr2C6H3)NC(R)}2CH, R = Me, tBu) with 1 equiv ofExpand