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Cross-coupling of aromatic bromides with allylic silanolate salts.
  • S. Denmark, N. Werner
  • Chemistry, Medicine
  • Journal of the American Chemical Society
  • 3 December 2008
The sodium salts of allyldimethylsilanol and 2-butenyldimethylsilanol undergo palladium-catalyzed cross-coupling with a wide variety of aryl bromides to afford allylated and crotylated arenes. TheExpand
  • 65
On the stereochemical course of palladium-catalyzed cross-coupling of allylic silanolate salts with aromatic bromides.
  • S. Denmark, N. Werner
  • Chemistry, Medicine
  • Journal of the American Chemical Society
  • 17 February 2010
The stereochemical course of palladium-catalyzed cross-coupling reactions of an enantioenriched, alpha-substituted, allylic silanolate salt with aromatic bromides has been investigated. The allylicExpand
  • 47
Cross‐Coupling with Organosilicon Compounds
Organosilicon functions possess many properties that make them ideal donors of organic groups in cross-coupling reactions. Through the addition of an appropriate silicophilic Lewis base, an in situExpand
  • 17
γ-Selective cross-coupling of allylic silanolate salts with aromatic bromides using trialkylphosphonium tetrafluoroborate salts prepared directly from phosphine•borane adducts.
The γ-selective, palladium-catalyzed cross-coupling of sodium (Z)-2-butenyldiethylsilanolate with a variety of aromatic bromides is reported. The protocol provides high yields (73-94%) and siteExpand
  • 20
Motion Planning for Climbing Mobility with Implementation on a Wall-Climbing Robot
TLDR
This paper proposes a planning framework that poses kinematic climbing planning as a discrete optimal planning problem. Expand
  • 1