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Histological detection of catalytic ferrous iron with the selective turn-on fluorescent probe RhoNox-1 in a Fenton reaction-based rat renal carcinogenesis model
Abstract Iron overload of a chronic nature has been associated with a wide variety of human diseases, including infection, carcinogenesis, and atherosclerosis. Recently, a highly specific turn-on… Expand
Rhodium-Catalyzed Synthesis and Optical Properties of Silicon-Bridged Arylpyridines.
A convergent and regioselective synthesis of silicon-bridged 4-arylpyridines has been developed through a rhodium-catalyzed [2+2+2] cycloaddition of silicon-containing diynes with nitriles. The… Expand
Synthesis of Quinoidal Fused Oligosiloles by Rhodium-Catalyzed Stitching Reaction and Theoretical Investigation of Their Properties.
- R. Shintani, N. Misawa, +4 authors K. Nozaki
- Chemistry, Medicine
- Journal of the American Chemical Society
- 1 March 2017
New quinoidal fused oligosiloles containing an even number of silole units have been synthesized by a rhodium-catalyzed stitching reaction. Employing [RhCl(tfb)]2 as the catalyst significantly… Expand
Palladium-Catalyzed Intramolecular C-H Arylation versus 1,5-Palladium Migration: A Theoretical Investigation.
- N. Misawa, T. Tsuda, R. Shintani, K. Yamashita, K. Nozaki
- Chemistry, Medicine
- Chemistry, an Asian journal
- 4 September 2018
Theoretical investigations were carried out to elucidate the origin of chemoselectivity in the palladium-catalyzed reactions of 2-(dimethylphenylsilyl)phenyl triflates with or without an amino group… Expand
Atomistic Simulation of the Polymerization Reaction by a (Pyridylamido)hafnium(IV) Catalyst: Counteranion Influence on the Reaction Rate and the Living Character of the Catalytic System.
- N. Misawa, Y. Suzuki, Kentaro Matsumoto, S. Saha, N. Koga, M. Nagaoka
- The journal of physical chemistry. B
- 27 January 2021
Atomistic simulation of the 1-octene polymerization reaction by a (pyridylamido)Hf(IV) catalyst was conducted on the basis of Red Moon (RM) methodology, focusing on the effect of the counteranions… Expand
A Selective Approach for the Synthesis of Functional Oligosiloles
Theoretical Study on the Mechanism of Palladium-Catalyzed Synthesis of 5,10-Dihydrophenazasilines via 1,5-Palladium Migration
Origin of Unusual Dependencies of LUMO Levels on Conjugation Length in Quinoidal Fused Oligosiloles