N. Lwoff

Publications9
h-index5
Citations77
Highly Influential Citations0
Claim Author Page
Author pages are created from data sourced from our academic publisher partnerships and public sources.

Recommended Authors

  • A. Viso
  • 160 Publications • 2,269 Citations
  • T. Donohoe
  • 392 Publications • 6,287 Citations
  • R. F. D. L. Pradilla
  • 138 Publications • 1,276 Citations
  • M. Tortosa
  • 83 Publications • 1,744 Citations
  • Publications
  • Influence
[2,3]-Sigmatropic rearrangements of 3-sulfinyl dihydropyrans: application to the syntheses of the cores of ent-dysiherbaine and deoxymalayamicin A.
The [2,3]-sigmatropic rearrangement of a variety of configurationally stable diastereomeric allylic sulfinyl dihydropyrans, produced by base-promoted cyclization of sulfinyl dienols, has been…
Sulfur-directed enantioselective synthesis of functionalized dihydropyrans.
TLDR
The highly selective base-promoted cyclization of enantiopure sulfinyl dienols affords allylic dihydropyranyl sulfones and sulfoximines in S(N)2' processes with organocuprates, and the reactivity of these products to dihydroxylation opens new possibilities to access enantio- and stereoselectivityated tetrahydropyrans that could be of interest for the synthesis of natural products.
Formal synthesis of ent-dysiherbaine from sulfinyl dihydropyrans by sigmatropic rearrangement and tethered aminohydroxylation
Stereoselective Functionalization of Dihydropyran‐3‐ols: Application to the Synthesis of Enantiopure Ethyl Deoxymonate B
Funded by: Direccion General de Investigacion, Ministerio de Educacion y Ciencia (DGI-MEC); Grant Number: CTQ2006-04522/BQU Comunidad de Madrid; Grant Number: S-SAL-0249-2006 Ministerio de…
Synthesis of enantiopure ethyl deoxymonate B from allylic sulfinyl dihydropyrans
Formal Synthesis of ent-Dysiherbaine from Sulfinyl Dihydropyrans by Sigmatropic Rearrangement and Tethered Aminohydroxylation.
Sulfur‐Directed Enantioselective Synthesis of Functionalized Dihydropyrans.
Synthesis of Ethyl Deoxymonate B
Highly Diastereoselective [3+2] Cycloadditions Between Non-Racemic p-Tolylsulfinimines and Iminoesters: An Efficient Entry to Enantiopure Imidazolidines and Vicinal Diaminoalcohols
TLDR
P-tolylsulfinimines undergo highly stereoselective [3 + 2] cycloadditions with azomethine ylides generated from α -iminoesters and LDA to produce N-sulfinylimidazolidines, which have been transformed into examples of a novel class of nonsymmetrical vicinal diamines using reductive and/or hydrolytic protocols.