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Electrochemistry and spectroscopy of organometallic terpyridine nickel complexes.
Organonickel complexes [(R'terpy)Ni(aryl)]X (R'terpy = derivatives of 2,2';6',2''-terpyridine; aryl = 2,6-dimethylphenyl = Xyl or 2,4,6-trimethylphenyl = Mes; X = Br or PF(6)) have been investigatedExpand
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Silanol-based surfactants: synthetic access and properties of an innovative class of environmentally benign detergents.
Herein, environmentally friendly surfactants based on new silanols as substitutes for the isoelectronic phosphonates were explored. Surface tensions of aqueous solutions are significantly reduced,Expand
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Silanetriols as in vitro inhibitors for AChE
Graphical abstract
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Surface modifications using a water-stable silanetriol in neutral aqueous media.
Surface modifications of glass slides employing the sterically hindered tert-butyl substituted silanetriol are described. To the best of our knowledge, this is the first time that a stableExpand
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Silanetriols as Powerful Starting Materials for Selective Condensation to Bulky POSS Cages
Controlled condensation reactions of tertiary silanetriols CH3(CH2)n(CH3)2CSi(OH)3 (1b–f; n = 1–5) in the presence of trifluoroacetic acid and the hydrolysis of CH3(CH2)6(CH3)2CSiCl3 (3) lead to theExpand
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Dimer formation upon deprotonation: synthesis and structure of a m-terphenyl substituted (R,S)-dilithium disiloxanolate disilanol.
The synthesis and structural characterization of the first dilithium salt of a tetrahydroxydisiloxane, [DmpSi(OH)OLi]2O (6), is described (Dmp = 2,6-dimesitylphenyl). The solid state structureExpand
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Back‐bonding in Organonickel Complexes with Terpyridine Ligands – A Structural Approach
A series of organonickel complexes [(R′terpy)Ni(aryl)]X (R′terpy = derivatives of 2,2′;6′,6″-terpyridine; R′ = 4-H, 4-Cl, 4-Tol and 4,4′,4″-tBu3; aryl = 2,6-dimethylphenyl = Xyl orExpand
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Mono- and Binuclear Arylnickel Complexes of the α-Diimine Bridging Ligand 2,2'-Bipyrimidine (bpym)
The mono- and binuclear organometallic Ni II complexes [(μ-bpym){Ni(Mes)Br} n ] (bpym = 2,2'-bipyrimidine; n = 1 or 2; Mes = mesityl = 2,4,6-trimethylphenyl) were prepared and characterisedExpand
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Binuclear Arylnickel Complexes with Bridging Bis(arylimino)-1,4-pyrazine Ligands
Binuclear organometallic nickel complexes of the type [(μ-NN){Ni(Mes)Br}2] {NN = α-diimine chelate ligand of the type 2,5-bis[1-(aryl)iminoethyl]pyrazine; Mes = mesityl = 2,4,6-trimethylphenyl} haveExpand
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At the Edge of Stability – Preparation of Methyl‐substituted Arylsilanetriols and Investigation of their Condensation Behavior
A series of arylsilanetriols [Aryl–Si(OH)3, Aryl = 2,6-dimethylphenyl, 2,4,6-trimethylphenyl 2,3,5,6-tetramethylphenyl] with two, three, and four methyl groups at the phenyl ring was prepared fromExpand
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