Nébéwia Griffete

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Inverse opal films of molecularly imprinted polymers (MIP) were elaborated using the colloidal crystal template method. The colloidal crystals of silica particles were built by the Langmuir-Blodgett technique, allowing a perfect control of the film thickness. Polymerization in the interspaces of the colloidal crystal in the presence of bisphenol A (BPA) and(More)
This paper reports the preparation of a molecularly imprinted inverse opal hydrogel containing a 2D defect layer, by combining the Langmuir-Blodgett technique and the photonic crystal template method. By coupling the exceptional characteristics of molecularly imprinted polymers, sensitive to the presence of a target molecule, and those of photonic crystals(More)
Core-shell particles of poly(styrene/alpha-tert-butoxy-omega-vinylbenzylpolyglycidol) P(S/PGL) were used as new building blocks for the assembly of a colloidal crystal. The added-value properties of these particles for photonic crystal architectures are their high hydrophilicity together with their thermoresponsivity. Indeed, the poglycidol-rich shell(More)
An innovative magnetic delivery nanomaterial for triggered cancer therapy showing active control over drug release by using an alternative magnetic field is proposed. In vitro and In vivo release of doxorubicin (DOX) were investigated and showed a massive DOX release under an alternative magnetic field without temperature elevation of the medium.
Optical properties of polymer microspheres with polystyrene cores and polyglycidol-enriched shells poly (styrene/α-tert-butoxy-ω-vinylbenzyl-polyglycidol) (P(S/ PGL) particles with number average diameters Dn determined by scanning electron microscopy equal 237 and 271 nm), were studied before and after immobilization of ovalbumin. The particles were(More)
Bulk imprinting of proteins was used combined with a grafting approach onto maghemite nanoparticles to develop a faster and simpler polymerization method for the synthesis of magnetic protein imprinted polymers with very high adsorption capacities and very strong affinity constants.
This communication describes the first example of the efficient use of a simple amphiphilic molecule as both a surfactant and an initiator in the miniemulsion polymerization of methyl methacrylate under AGET and ARGET ATRP conditions.
We demonstrate that the reaction of amino modified particles with tert-butylnitrite can provide diazonium surface functionality which itself is highly reactive with iron oxide nanoparticles in basic media. Using this strategy we synthesize a magnetic hybrid material with dense covalent attachment of magnetic iron oxide nanoparticles on the silica surface.(More)
A novel and facile methodology for the in situ surface functionalization of Fe(3)O(4) nanoparticles is proposed, based on the use of aryl diazonium salts chemistry. The grafting reaction involves the formation of diazoates in a basic medium. These species are unstable and dediazonize along a homolytic pathway to give aryl radicals which further react with(More)
We investigated different methods to engineer efficiently a planar defect between two artificial opals. The samples were characterized by atomic force microscopy, scanning electron microscopy and specular reflection spectroscopy. They presented pronounced defect modes within the photonic stopband. These architectured structures were applied to the(More)