Myriam Campos

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The enthalpies of solution, Delta(sol)H(m), for 5,10,15,20-tetraphenylporphine (CA registry number 917-23-7, TPP), 5,10,15,20-tetraphenylporphine of Co(II), Ni(II), Cu(II), and Zn(II) (to be written as CoTPP, NiTPP, CuTPP, and ZnTPP) in chloroform, were calorimetrically measured at T = 298 K in the concentration ranging from 3.5 x 10(-5) to 2.8 x 10(-4)(More)
The compound, 5,10,15,20-tetrakis(4-methoxyphenyl)porphine zinc(II) (ZnTMPP), was prepared, and its thermochemical properties were experimentally established. The standard molar energy of combustion (Delta(c)U degrees m) was determined from oxygen rotating-bomb combustion calorimetry experiments. The standard molar enthalpies of combustion (Delta(c)H(More)
Captodative olefins are highly reactive and selective substrates in Diels-Alder and 1,3-dipolar cycloadditions. Seeking an explanation of this fact based on molecular energetics, the thermochemical analysis of 1-acetyl vinyl p-nitrobenzoate, a captodative olefin, has been performed using semi-micro-combustion calorimetry, effusion measurements through a(More)
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