Muthupandi Nagaraj

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Three strikes aN2d you’re out! The spontaneous azide decomposition on mononuclear ruthenium complexes bearing a redox-active aminophenol-derived tridentate NNO ligand selectively generates a rare trinuclear complex with an unsymmetric Ru=N¢Ru¢N=Ru skeleton, proposedly by oxidative nitride coupling. DFT and experimental data support a pivotal role for the(More)
A novel strategy of copper(I)-catalyzed cascade intramolecular nucleophilic attack on N-sulfonylketenimine followed by rearrangement of sulfonimidates to sulfonamides resulting in a library of substituted 8,9-dihydro-5H-imidazo[1,2-a][1,4]diazepin-7(6H)-ones has been developed.
A simple and efficient protocol for the construction of substituted piperazines, piperidines, thiomorpholines, decahydroquinolines, perhydrocyclopenta[b]pyridine, and pyrrolidines bearing N-hydroxy substituents through intramolecular reductive cyclization of diketoximes using sodium cyanoborohydride is described.
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