In the asymmetric unit of the title complex, [Ni(C16H14N3OS)2], the nickel ion is tetra-coordinated in a distorted square-planar geometry by two independent mol-ecules of the ligand which act as mononegative bidentate N,S-donors and form two five-membered chelate rings. The ligands are in trans (E) conformations with respect to the C=N bonds. The close… (More)
In the title compound, [PdBr(C(27)H(23)N(3)OPS)]·C(3)H(6)O, the coordination geometry about the Pd(II) atom is distorted square-planar, arising from the attached Br, S, P and N atoms (N and Br are trans), the maximum deviation from the plane being 0.2053 (4) Å for the N atom. The three benzene rings attached to the P atom make dihedral angles of 69.78 (7),… (More)
The address of one of the authors in the paper by Salam et al.
The monodeprotonated Schiff base ligand in the title compound, [Sn(CH(3))(C(14)H(19)N(4)S)Cl(2)], N,N',S-chelates to the Sn atom, which is six-coordinated in an octa-hedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond… (More)
The asymmetric unit of the title complex, [Pd(C(19)H(20)N(2)O(2))]·0.5C(2)H(5)OH, contains two mol-ecules of a Pd(II) complex of a Schiff base ligand with an N(2)O(2) donor set and one ethanol mol-ecule. The Pd(II) centers are in distorted square-planar geometries with the N(2)O(2) donor atoms of the tetra-dentate Schiff base dianions. The ethanol mol-ecule… (More)