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Journals and Conferences
N,N'-dimethyl-2,3-dialkylpyrazinium salts show reversible transitions between all redox stages and a monolayer formation at the air-water interface that suggests their use as redox-switchable surfactants.
The kinetics of radical heterolysis reactions, including rate constants for radical cation-anion contact ion pair formation, collapse of the contact pair back to the parent radical, and separation of the contact pair to a solvent-separated ion pair or free ions were obtained in several solvents for a beta-mesyloxy radical. Rate constants were determined… (More)
[reaction: see text] A design for fast kinetic studies of electron transfer in radical anions is reported. alpha-Hydroxy radicals formed by 355 nm laser flash photolysis of alpha-phenacyl alcohols are deprotonated under basic conditions to give ketyl radical anions that serve as electron injectors in inter- and intramolecular electron-transfer reactions.… (More)