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A novel C(2)-symmetric 2,6-diallylpiperidine carboxylic acid methyl ester as a promising chiral building block for piperidine-related alkaloids.
C(2)-symmetric 2,6-diallylpiperidine 1-carboxylic acid methyl ester (5) was examined via the double asymmetric allylboration of glutaraldehyde followed by aminocyclization and carbamation as aExpand
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Fragmentation of tertiary cyclopropanol compounds catalyzed by vanadyl acetylacetonate
Tertiary cyclopropanol compounds react with a catalytic amount of vanadyl acetylacetonate in the presence of oxygen affording β-hydroxyketones and β-diketones. ForExpand
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A new route to trans-2,6-disubstituted piperidine-related alkaloids using a novel C2-symmetric 2,6-diallylpiperidine carboxylic acid methyl ester.
A novel C2-symmetric 2,6-diallylpiperidine carboxylic acid methyl ester 1 was prepared by the double asymmetric allylboration of glutaldehyde followed by an aminocyclization and carbamation. On theExpand
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A Concise Synthesis of (+)-Indolizidine 209D Using a C2-Symmetric 2,6-Diallylpiperidine
An asymmetric synthesis of (+)-indolizidine 209D (2) using C- 2 -symmetric 2,6-diallylpiperidine (1) as a chiral building block is presented in a straightforward fashion.
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