Mohammad Hedayetullah Mir

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A new form of water aggregate, viz., (H(2)O)(7) helicate, has been trapped between the ClO(4)(-) anions in the channels of a diamondoid metal-organic framework (MOF) where a small change in the structure of the backbone of the MOF from 1,10-phenanthroline to a 2,2'-bipyridine ligand transforms the cyclic to an acyclic water helicate.
Two different three-dimensional interpenetrating metal-organic frameworks, {[Co(bpe)(muco)](DMF)(H 2O)} n ( 1) and {[Co(bpe)(muco)(H 2O) 2].4(H 2O)} n ( 2) [bpe = 4,4'-bipyridyl ethylene, H 2-muco = trans,trans-muconic acid, DMF = dimethyl formamide] have been co-crystallized in one-pot reaction. This work offers some insights into the intricacy of(More)
Photochemical [2+2] cycloaddition reactions in a two-dimensional interdigitated porous crystalline framework proceed in a single-crystal-to-single-crystal manner, and one-dimensional channels show structural changes that have a significant impact on the CO(2) sorption.
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