Minsul Jang

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Fluorous phases show unique properties different from those of common aqueous or organic phases and have a variety of uses in purification, separation, and reaction control. Typically, fluorous solvents are employed to provide a bulk fluorous phase, but microscopic fluorous phases can be generated by attaching fluorous chains on such scaffolds as polymers,(More)
An efficient nickel catalyst system for the carboxylation of organozinc reagents with CO(2) under very mild conditions has been developed. The catalyst system complements the conventional methods and enables the direct synthesis of various saturated carboxylic acid derivatives from the corresponding alkylzinc reagents and CO(2).
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