Mikiyas K Assefa

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Reaction of [UO2(N(SiMe3)2)2(THF)2] with 1 equiv of dibenzotetramethyltetraaza[14]annulene (tmtaaH2) affords the uranyl complex [UO2(tmtaaH)(N(SiMe3)2) (THF)] (1) (THF = tetrahydrofuran) as red blocks in 83% yield. Similarly, thermolysis of a mixture of [UO2(N(SiMe3)2)2(THF)2] and 2 equiv of tmtaaH2 affords [UO2(tmtaaH)2] (2), which can be isolated as(More)
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