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Journals and Conferences
Synthesis, structure determination by single-crystal X-ray diffraction, and physical properties are reported and compared for superconducting and semiconducting molecular charge-transfer salts with stoichiometry (BEDT-TTF)(4)[A(I)M(III)(C(2)O(4))(3)].PhCN, where A(I) = H(3)O, NH(4), K; M(III) = Cr, Fe, Co, Al; BEDT-TTF = bis(ethylenedithio)… (More)
[reaction: see text] A new Kekulé polycyclic hydrocarbon with a singlet biradical index of 50% was synthesized. The singlet biradical character was assessed with UV and 1H-NMR spectroscopy, cyclic voltammetry, SQUID magnetic susceptibility measurement, and quantum chemical calculations.
We reinvestigated the two C=C stretching modes of the five-membered rings of ET (ET = bis(ethylenedithio)tetrathiafulvalene), namely, nu(2) (in-phase mode) and nu(27) (out-of-phase mode). The frequency of the nu(27) mode of ET(+) was corrected to be approximately 1400 cm(-1), which was identified from the polarized infrared reflectance spectra of… (More)
We have examined time-averaged charges of the molecular donors around the phase boundary between the insulating, superconducting, and metal phases for -type ET ET=bis-ethelenedithio-tetrathiafulvalene salts with one two hole s per two three molecules by using vibrational spectroscopy. Around the phase boundary, the site charges are neither those expected… (More)
Photoirradiation of a solution of BH(3).NHR(2) (1a: R = Me, 1b: R = 1/2C(4)H(8), 1c: R = 1/2C(5)H(10), 1f: R = Et) containing a catalytic amount of a group-6 metal carbonyl complex, [M(CO)(6)] (M = Cr, Mo, W), led to dehydrogenative B-N covalent bond formation to produce aminoborane dimers, [BH(2)NR(2)](2) (2a-c, f), in high yield. During these reactions a… (More)
A novel naphthoquinoid singlet biradical (2a) stabilized by phenalenyl rings is prepared by a multistep procedure and is investigated in terms of covalent bonding interactions. The molecule 2a gives single crystals, in which a 1D chain is formed with a very short π-π contact at the overlapping phenalenyl rings. The unpaired electrons in 2a are involved in… (More)
We We present the temperature dependences of the reflectance and Raman spectra of metallic β -(BEDT-TTF)(TCNQ). BEDT-TTF and TCNQ form quasi-one-dimensional bands mainly extended along the aand c-axes, respectively, and their interaction along the b-axis is weak. The degree of charge transfer from BEDT-TTF to TCNQ is about 0.5, so that each band forms a… (More)
[Dineopentyl-biferrocene]2[Cl1TCNQ]7, which has an unprecedented high donor-acceptor ratio of 2 : 7, contains a linear paramagnetic hexamer of Cl1TCNQ. Both the donor and acceptor molecules exhibit charge disproportionation in the crystal through mutual electrostatic interactions.