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Luminescence of LnIII dithiocarbamate complexes (Ln = La, Pr, Sm, Eu, Gd, Tb, Dy).
We have discovered room temperature photoluminescence in Sm3+ and Pr3+ dithiocarbamate complexes. Surprisingly, these complexes exhibit more intense emission than those of the Eu3+, Tb3+, and Dy3+Expand
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Mono- and Trinuclear Nickel(II) Complexes with Sulfur-Containing Oxime Ligands: Uncommon Templated Coupling of Oxime with Nitrile.
4,7-Dithiadecane-2,9-dione dioxime forms both violet and purple-black nickel(II) complexes with unexpected structural properties, quite unlike the square-planar chelates formed by its dithiaundecaneExpand
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Structural, magnetic and related attributes of some oximate-bridged tetranuclear nickel(ii) rhombs and a dinuclear congenerElectronic supplementary information (ESI) available: mass spectra, χT vs.
New oximate-bridged tetranuclear nickel(II) complexes of compositions {Ni(Dien)}2(μ3-OH)2{Ni2(Moda)4}(ClO4)2·Solv (Solv = H2O, 1a; Solv = 2CH3NO2, 1b; Solv = 2H2O·2C4H8O2, 1c),Expand
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A Tetrameric Nickel(II) "Chair" with both Antiferromagnetic Internal Coupling and Ferromagnetic Spin Alignment A.W.A. and M.J.P. thank Drexel University for support.
Interest in polynuclear complexes of the 3d metals has been stimulated by the search for new magnetic materials[1, 2] and by demonstration of the occurrence of oligonuclear metal centers in proteinsExpand
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A nickel(II) di-μ2-phenolato bridged dinuclear complex: Weak antiferromagnetic interactions in nickel(II) dimers
Abstract [Ni(dpmap)(H 2 O)] 2 (ClO 4 ) 2  · 3(CH 3 ) 2 CO, a dinuclear nickel(II) complex of 2-{[[Di(2-pyridyl)methyl](methyl)amino]methyl}phenol, dpmapH has been synthesized. X-ray diffractionExpand
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A new class of macrocyclic complexes formed via nickel-promoted macrocyclisation of dioxime with dinitrile.
o-Phthalonitrile couples with chelating dioxime on nickel(II), with formation of a dinuclear nickel(II) macrocyclic complex--the first representative of a new class of imine-appended macrocycles.
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A tetranuclear copper(II) complex with bis(o-aminobenzaldehyde)thiocarbohydrazone
Abstract Bis(o-aminobenzaldehyde)thiocarbohydrazone (HL) forms with copper(II) nitrate a tetranuclear complex [Cu2(L)(NO3)3]2·2H2O, in which two dinuclear units are joined by nitrate bridges. TheExpand
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Luminescence and Nonlinear Optical Properties in Copper(I) Halide Extended Networks.
The syntheses, structures, and luminescence properties of a series of copper(I) halide coordination polymers, prepared with mono- and bidentate N-heteroaromatic ligands, are reported. TheseExpand
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Copper(II) complexes of tetradentate thioether-oxime ligands
Abstract Two dinuclear copper(II) thioether-oxime complexes ([Cu(DtdoH)]2(ClO4)2 and [Cu(DtudH)]2(ClO4)2 · 2CH3OH) have been synthesized. [Cu(DtdoH)]2(ClO4)2 reacted with excess BF3 · OEt2 to yieldExpand
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Pentadentate thioether-oxime macrocyclic and quasi-macrocyclic complexes of copper(II) and nickel(II)
Abstract A series of new pentadentate thioether-oximes (TtoxH2, MeTtoxH2, OdtoxH2) were synthesized along with their Ni(II) and Cu(II) complexes. BF2 +-bridging is accomplished by reaction of theExpand
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