Michael D Hoops

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Matrix isolation studies, combined with infrared spectroscopy, of the twin jet codeposition of ozone into matrices containing either cyclopentadiene or cyclopentene have led to the first observation of several early intermediates in these ozonolysis reactions. Specifically, evidence is presented for the formation, identification, and characterization of the(More)
The matrix isolation technique has been combined with infrared spectroscopy and theoretical calculations to characterize the products of the photochemical and thermal reactions of cyclopentadiene, cyclopentene, cyclopentane, and cyclopropane with CrCl 2O 2. While initial twin jet deposition of the reagents led to no visible changes in the recorded spectra,(More)
The matrix isolation technique, combined with infrared spectroscopy, has been used to characterize the products of the photochemical reactions of benzene with CrCl(2)O(2) and OVCl(3). While initial twin jet deposition of the reagents led to no visible changes in the recorded spectra, strong product bands were noted following irradiation with light of lambda(More)
The matrix isolation technique, combined with infrared spectroscopy, has been used to characterize the products of the photochemical reactions of toluene, m-, o-, and p-xylene, mesitylene, and hexamethylbenzene with CrCl2O2. While initial twin jet deposition of the reagents led to no visible changes in the recorded spectra, strong product bands were noted(More)
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