Megumi Okuhata

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In recent years, solvate and protic ionic liquids (ILs) have attracted much attention. We synthesized both types of ILs from alkyl aza-crown ethers (L = N-propyl-1-aza-15-crown-5 (L1) and N-C6F13C2H4-1-aza-15-crown-5 (L2)). The solvate ILs [ML][Tf2N] (M = Na+, K+) were solids (Tm = 58-68 °C), whereas the solvate ILs [ML][Tf2N] (M = Li+, Ag+) and protic ILs(More)
A thermochromic magnetic ionic liquid containing a cationic iron(III) Schiff-base complex has been developed, whose color and magnetic moment change with temperature because of spin crossover in the liquid state. This spin-crossover behavior closely resembles that of a solid having the same cation.
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