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Electrochemical Arylation Reaction.
TLDR
The electrochemical formation of the aryl-substrate bond is discussed for aromatic substrates, heterocycles, other multiple bond systems, and even at saturated carbon substrates. Expand
Electrochemical Allylic Oxidation of Olefins: Sustainable and Safe.
TLDR
The allylic oxidation of olefins, which is an important C-H activation process that provides access to enones, becomes a sustainable, versatile, and potent key reaction for organic synthesis. Expand
A Novel Cathode Material for Cathodic Dehalogenation of 1,1-Dibromo Cyclopropane Derivatives.
TLDR
The electroorganic conversion tolerates a variety of functional groups and can be conducted at rather complex substrates like cyclosporine A, which allows the sustainable preparation of cyclopropane derivatives. Expand
Total Synthesis of (-)-Oxycodone via Anodic Aryl-Aryl Coupling.
TLDR
A fully regio- and diastereoselective electrochemical 4a-2'-coupling of a 3',4',5'-trioxygenated laudanosine derivative enables the synthesis of the corresponding morphinandienone, providing high yields and under constant current conditions both in a simple undivided cell or in continuous flow. Expand
Large, Highly Modular Narrow-Gap Electrolytic Flow Cell and Application in Dehydrogenative Cross-Coupling of Phenols
The successive scale-up of electrochemical reactions is crucial with regard to the implementation of technical electro-organic syntheses. Therefore, we developed a scalable modular parallel-plate e...
Selective and Scalable Dehydrogenative Electrochemical Synthesis of 3,3′,5,5′-Tetramethyl-2,2′-biphenol
3,3′,5,5′-Tetramethyl-2,2′-biphenol is a compound of high technical significance, as it exhibits superior properties as building block for ligands in the transition-metal catalysis. However, sideExpand
Supporting-Electrolyte-Free and Scalable Flow Process for the Electrochemical Synthesis of 3,3′,5,5′-Tetramethyl-2,2′-biphenol
The most efficient electrochemical synthesis of 3,3',5,5'-tetramethyl-2,2'-biphenol by dehydrogenative coupling is reported. The electrolysis is performed supporting electrolyte-free in 1,1,1,3,3,3...
Electrosynthesis of 3,3′,5,5’-Tetramethyl-2,2′-biphenol in Flow
3,3′,5,5’-Tetramethyl-2,2′-biphenol is well known as an outstanding building block for ligands in transition-metal catalysis and is therefore of particular industrial interest. The electro-organicExpand
Developments in the Dehydrogenative Electrochemical Synthesis of 3,3′,5,5′‐Tetramethyl‐2,2′‐biphenol
TLDR
The electro‐organic method is a powerful, sustainable, and efficient alternative to conventional synthesis to obtain this symmetric biphenol up to the kilogram scale. Expand
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