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Journals and Conferences
Highly fluorinated tris(pyrazolyl)borate ligand [HB(3,5-(CF3)2Pz)3]- has been used in the isolation of air- and light-stable silver complex, [HB(3,5-(CF3)2Pz)3]Ag(OSMe2). It is a monomeric tetrahedral silver complex with an O-bonded dimethylsulfoxide ligand. The silver adduct [HB(3,5-(CF3)2Pz)3]Ag(OSMe2) and the related [HB(3,5-(CF3)2Pz)3] Ag(THF) (where… (More)
New [CpM(Q)Cl] complexes (M = Rh or Ir, Cp = pentamethylcyclopentadienyl, HQ = 1-phenyl-3-methyl-4R(C=O)-pyrazol-5-one in general, in detail HQ(Me), R = CH(3); HQ(Et), R = CH(2)CH(3); HQ(Piv), R = CH(2)-C(CH(3))(3); HQ(Bn), R = CH(2)-(C(6)H(5)); HQ(S), R = CH-(C(6)H(5))(2)) have been synthesized from the reaction of [CpMCl(2)](2) with the sodium salt, NaQ,… (More)
Two rare copper complexes, a tri-alkene adduct [Cu(ttt-cdt)(FSbF(5))] and a non-classical carbon monoxide complex [Cu(ttt-cdt)(CO)][SbF(6)] with a high CO stretching frequency ([small nu, Greek, macron](CO) = 2160 cm(-1)), have been isolated using trans,trans,trans-1,5,9-cyclododecatriene (ttt-cdt) ligand.
Highly fluorinated tris(pyrazolyl)borates were tested for their antimicrobial activity against various bacterial species. Both the silver(I) tris(pyrazolyl)borate [HB(3,5-(CF(3))(2)Pz)(3)]Ag(THF) (THF=tetrahydrofuran) and the sodium analog [HB(3,5-(CF(3))(2)Pz)(3)]Na(THF) appeared highly effective at inhibiting the growth of two different species of… (More)
Three closely related organometallic "spoke-wheel" complexes featuring coinage metal ions, Au(I), Ag(I), and Cu(I), bonded to three norbornene molecules in trigonal planar fashion have been isolated and completely characterized using several methods including X-ray crystallography.