Maurizio Fagnoni

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The storage of solar energy is one of the main challenges in the near future. A rather unexploited way to fulfil this goal is the solar light induced formation of new chemical bonds, i.e. the synthesis of chemicals. Solar photons can be considered the ideal green reagents since they are costless and leave no residue in the reaction mixture. In many cases(More)
An important goal of modern organic chemistry is to develop new catalytic strategies for enantioselective carbon-carbon bond formation that can be used to generate quaternary stereogenic centres. Whereas considerable advances have been achieved by exploiting polar reactivity, radical transformations have been far less successful. This is despite the fact(More)
Steady-state irradiation in neat acetonitrile of some aromatic nitriles, imides and esters (10(-5)-10(-3) M solution) in the presence of tertiary amines allowed the accumulation of the corresponding radical anions, up to quantitative yield for polysubstituted benzenes and partially with naphthalene and anthracene derivatives. The condition for such an(More)
UV absorption spectra of the Lindqvist polyoxometalate [W(6)O(19)](2-) were predicted by relativistic time-dependent density functional theory with several combinations of density functional and basis set. Hybrid functionals with frozen-core Slater basis sets were found to provide the best agreement with experiment while keeping reasonable computational(More)
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