— We report improved stabilization results for and progress toward a more accurate frequency measurement of the 532 nm iodine-stabilized system based on a frequency-doubled Nd : YAG ring laser. We confirm the CCL-adopted frequency well within its stated uncertainty (640 kHz).
A rapidly-swept external-cavity quantum cascade laser with an open-path Herriott cell is used to quantify gas-phase chemical mixtures of D 2 O and HDO at a rate of 40 Hz (25-ms measurement time). The chemical mixtures were generated by evaporating D 2 O liquid near the open-path Herriott cell, allowing the H/D exchange reaction with ambient H 2 O to produce… (More)
The small size, high power, promise of access to any wavelength between 3.5 and 16 microns, substantial tuning range about a chosen center wavelength, and general robustness of quantum cascade (QC) lasers provide opportunities for new approaches to ultra-sensitive chemical detection and other applications in the mid-wave infrared. PNNL is developing novel… (More)