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The selective oxidation of ethylene glycol and 1,2-propanediol on Au, Pd, and Au–Pd bimetallic catalysts
- Michael B. Griffin, A. A. Rodríguez, Matthew M Montemore, J. Monnier, C. Williams, J. W. Medlin
- 1 November 2013
Abstract The oxidation of ethylene glycol (HOCH 2 CH 2 OH) and 1,2-propanediol (HOCH(CH 3 )CH 2 OH) was investigated over Pd/C, Au/C, and a series of bimetallic catalysts prepared by electroless… Expand
How Does Nanoporous Gold Dissociate Molecular Oxygen
Nanoporous Au and other dilute AgAu alloys are highly active and selective oxidation catalysts. Their ability to dissociate O2 is to a large extent unexplained, given that unsupported Au cannot… Expand
Enhanced Dry Reforming of Methane on Ni and Ni-Pt Catalysts Synthesized by Atomic Layer Deposition
Abstract Atomic layer deposition (ALD) was used to deposit Ni and Pt on alumina supports to form monometallic and bimetallic catalysts with initial particle sizes of 1–2.4 nm. The ALD catalysts were… Expand
Scaling relations between adsorption energies for computational screening and design of catalysts
Adsorption energies have significant value as predictors of catalytic performance. An important method of increasing efficiency of adsorption energy calculations is to employ scaling relations, which… Expand
O2 Activation by Metal Surfaces: Implications for Bonding and Reactivity on Heterogeneous Catalysts.
- Matthew M Montemore, M. V. van Spronsen, R. J. Madix, C. Friend
- Chemistry, Medicine
- Chemical reviews
- 8 November 2017
The activation of O2 on metal surfaces is a critical process for heterogeneous catalysis and materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of techniques have… Expand
Direct visualization of quasi-ordered oxygen chain structures on Au(110)-(1 × 2)
Abstract The Au(110) surface offers unique advantages for atomically-resolved model studies of catalytic oxidation processes on gold. We investigate the adsorption of oxygen on Au(110) using a… Expand
A unified picture of adsorption on transition metals through different atoms.
- Matthew M Montemore, J. W. Medlin
- Chemistry, Medicine
- Journal of the American Chemical Society
- 2 July 2014
A key issue in catalyst design is understanding how adsorption energies of surface intermediates vary across both different surfaces and various types of adsorbing atoms. In this work, we examine… Expand
Predicting and Comparing C–M and O–M Bond Strengths for Adsorption on Transition Metal Surfaces
Understanding which surface properties control adsorption on metal surfaces has long been a primary goal in surface science and catalysis, for both fundamental and technological reasons. Moreover,… Expand
A density functional study of C1-C4 alkyl adsorption on Cu(111).
To better understand the nature of alkyl intermediates often invoked in reactions involving hydrocarbon reactants and products, the adsorption of linear and branched C(1)-C(4) alkyls on Cu(111) at… Expand
Site-Specific Scaling Relations for Hydrocarbon Adsorption on Hexagonal Transition Metal Surfaces
Screening a large number of surfaces for their catalytic performance remains a challenge, leading to the need for simple models to predict adsorption properties. To facilitate rapid prediction of h...